iam2681
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  • 13-10-2020
  • Chemistry
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Why is the primary standard, KHP, used in the determination of the molar mass of an acid?

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studentsmart2020
studentsmart2020 studentsmart2020
  • 13-10-2020

Potassium acid phthalate will serve as our primary standard. This is a large molecule (KHC8H4O4) with a molar mass of 204.2 g/mol. Instead of writing the whole formula, we abbreviate it as KHP, where "P" stands for the phthalate ion, C8H4O42-, not for phosphorus. KHP is an acidic substance, with the ionizing hydrogen being set forward in the formula for emphasis. Therefore, KHP is monoprotic and will react with NaOH in a simple 1 to 1 relationship according to the following equation:

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